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By J. H. Jones

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Les, and S. Rybak, J. Theor. , 1983, 104, 571. S. Millefiori and A. Millefiori, Theochem, 1983, 8 , 391. A. E. Smolyar, A. R. Abramov, A. A. Guliev, 0. N. Narimanbekov, and T. rJ. Shakhtakhtinskii, Azerb. Khim. , 1982, 2 0 . M. Charton and €3. I. Charton, J. Theor. ,1982, 99, 629. N . V. Kumar and G. Govil in 'Conformation in Biology', ed. R. Srinivasan and R. H. Sarma, Adenine Press, Guilderland, New York, 1983, p. 31 3. 272). 286 5 Chemical Studies of Amino Acids Racemization. - Papers describing mechanistic aspects of amino acid racemization argue in favour287 of a two-step process with abstraction of the methine proton being rate-determining.

Chem. C o m m u n . , 1983, 116. A. Koskinen, P. Somersalo, and M. Lounasmaa, Heterocycles, 1983, 20, 557. K. Wuethrich, M. Billeter, and W . Braun, J . Mol. , 1983, 169, 949. C. Rossi, L. Pogliani, F. Laschi, and N . Niccolai, J. Chem. , Faraday Trans. I , 1983, 79, 2955. S. Biagini, A. h i , M. Monduzzi, and G. Saba, J. Chem. , Faraday Trans. 2 , 1983, 79, 491. e. r. r. r. r. 232 The data can be used to indicate that in this environment approximately one-third of the guanidino form is present as the R N z C ( N H ~ )t~a ~ t o r n e r The .

T. Brown, D. Gold, J . Gordon, and P. D. Klein, Anal. , 1983,131,93. 181 Z. E. Kahana and A. Lapidot, Anal. , 1983, 132, 160. K. R. Barrio, F. J . Baumgartner, E. Henze, M. R. Stauber, J . E. Egbert, N. S. MacDonald, H. L. Schelbert, M. E. Phelps, and F. T. Liu, J. Nucl. , 1983, 24, 937. D. Jewett and R. Ehrenkaufer in ‘Proceedings of the International Symposium on Synthetic Applications of Isotopically Labelled Compounds’, ed. W. P. Duncan and A. B. Susan, Elsevier, Amsterdam, 1983, p. 205. 184 M.

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