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By William Skeen

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3 Notations and conventions The individual structures listed in the tables are named using standard notations, particularly for superlattices: we use Wood, “rect” (rectangular) or occasionally matrix notations for the superlattices, which are defined in many books and reviews [86V, 99W]; they appear in the exact form used in the Surface Structure Database [99W]. g. fcc-hollow site for adsorption at an fcclattice-continuation site above an fcc(111) surface. Figures are provided to clarify the more common adsorption sites and local adsorption geometries.

Volokitin, A. : Infrared reflection-absorption spectroscopy of dipoleforbidden adsorbate vibrations: Surf. Sci. 310 (1994) 314. , Liegener, C. : Angular-resolved autoionization study of CO on Ni(110): experiment and theory: Phys. Rev. B 49 (1994) 10557. Rieder, K. : Surface structural research with atom beam diffraction: helium versus neon: Surf. Rev. Lett. 1 (1994) 51. , Yannoni, C. , Kendrick, R. : Force detection of nuclear magnetic resonance: Science 264 (1994) 1560. : Adsorbate-substrate bonding and dynamics as determined by SEXAFS: J.

1 and 2, which define our generic labeling scheme applicable to all metallic substrates. The principle is to look from the adsorption site or axis outward, in any given layer. Consider the four coplanar and symmetrical light-grey substrate atoms depicted in Fig. 1, which looks down onto a particular atomic layer: these symmetry-equivalent atoms form a shell numbered s, at a radial distance rls from the (projected) adsorbate site (more precisely, this shell is cylindrical around the adsorbate site axis, which is very often an axis of rotational symmetry).

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